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Redox reaction of red phosphorus with hydrosulfide anions in DMSO

โœ Scribed by B. A. Trofimov; S. I. Verkhoturova; V. L. Mikhailenko; T. I. Kazantseva; S. N. Arbuzova; A. A. Tatarinova; L. V. Klyba; N. K. Gusarova


Book ID
111459810
Publisher
Springer
Year
2008
Tongue
English
Weight
150 KB
Volume
78
Category
Article
ISSN
1070-3632

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The reaction of red phosphorus with 1-br
โœ Vladimir A. Kuimov; Svetlana F. Malysheva; Nina K. Gusarova; Tamara I. Vakul'ska ๐Ÿ“‚ Article ๐Ÿ“… 2011 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 163 KB

## Abstract Red phosphorus reacts with 1โ€bromonaphthalene in the KOHโ€“DMSO system upon heating (47โ€“70ยฐC, 3 h) to give tri(1โ€naphthyl)phosphane in 10% yield. Microwave activation (600 W, 6 min) of the reaction affords the aboveโ€mentioned phosphane in 25% yield. ยฉ 2011 Wiley Periodicals, Inc. Heteroat