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The reaction of red phosphorus with 1-bromonaphthalene in the KOH–DMSO system: Synthesis of tri(1-naphthyl)phosphane

✍ Scribed by Vladimir A. Kuimov; Svetlana F. Malysheva; Nina K. Gusarova; Tamara I. Vakul'skaya; Spartak S. Khutsishvili; Boris A. Trofimov

Publisher: John Wiley and Sons
Year: 2011
Tongue: English
Weight: 163 KB
Volume: 22
Category: Article
ISSN: 1042-7163
DOI: 10.1002/hc.20671

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✦ Synopsis

Abstract

Red phosphorus reacts with 1‐bromonaphthalene in the KOH–DMSO system upon heating (47–70°C, 3 h) to give tri(1‐naphthyl)phosphane in 10% yield. Microwave activation (600 W, 6 min) of the reaction affords the above‐mentioned phosphane in 25% yield. © 2011 Wiley Periodicals, Inc. Heteroatom Chem 22:198–203, 2011; View this article online at wileyonlinelibrary.com. DOI 10.1002/hc.20671

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