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Redox-mesoporous molecular sieve as a bifunctional catalyst for the one-pot synthesis of campholenic aldehyde from α-pinene

✍ Scribed by Young-Woong Suh; Nam-Kyung Kim; Wha-Seung Ahn; Hyun-Ku Rhee


Book ID
104421504
Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
98 KB
Volume
174
Category
Article
ISSN
1381-1169

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## Abstract Reaction of an isocyanide with an electron‐poor aromatic aldehyde in the presence of silica nanoparticles (silica NP; __ca.__ 42 nm) proceeds smoothly at room temperature to afford 2‐hydroxyacetamide derivatives in high yields (__Scheme 1__ and __Table 1__).