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Redox kinetics of metal complexes in nonaqueous solutions: reductions of tris(1,10-phenanthroline)- and tris(2,2'-bipyridine)iron(III) by hexakis(N,N-dimethylformamide)iron(II) in acetonitrile: role of first-coordination sphere

โœ Scribed by Schmid, Roland; Kirchner, Karl; Dickert, Franz L.


Book ID
121453238
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
832 KB
Volume
27
Category
Article
ISSN
0020-1669

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Redox kinetics of metal complexes in non
โœ Roland Schmid; Valentin N. Sapunov ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 737 KB

The electron transfer step of the reduction of Mn(acac)s and Co(acac)s by Fe(I1) in acetonitrile is preceded by the one-ended dissociation of an acac ligand and the formation of a binuclear bridged complex. After the electron transfer has taken place through the bridging ligand, the complex dissocia