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Redox kinetics of metal complexes in nonaqueous solutions: Oxidation of a series of tris(1,10-phenanthroline)iron(II) ions by hexakis(trimethylphosphate)iron(III) in acetonitrile — A reactivity-selectivity relationship

✍ Scribed by R. Schmid; Liang-feng Han; K. Kirchner; V. N. Sapunov


Publisher
Springer Vienna
Year
1993
Tongue
English
Weight
972 KB
Volume
124
Category
Article
ISSN
0026-9247

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The natural decay of Fe(phen)33 § where no Ce w is employed for scavenging the side reaction product, Fe(phen)~ +, is now treated as a complex reaction involving two parallel processes, and the experimental kinetics are consistent with the rate laws derived from a mechanism that simultaneously expla