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Redox cycle of metal-on-active carbon catalyst in the vapor phase carbonylation of methanol

✍ Scribed by Hiroshi Yagita; Kaoru Fujimoto


Publisher
Elsevier Science
Year
1991
Weight
395 KB
Volume
69
Category
Article
ISSN
0304-5102

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The role of the promoter metals palladium and ruthenium in the mechanism of the hydrocarbonylation (reductive carbonylation) of methanol over cobalt/active carbon catalysts has been investigated. It has been found that the reduction steps on active Co sites are strongly affected by activated hydroge