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Characterization of catalyst in the synthesis of dimethyl carbonate by gas-phase oxidative carbonylation of methanol

โœ Scribed by Ruixia Jiang; Yanji Wang; Xinqiang Zhao; Shufang Wang; Changqing Jin; Chengfang Zhang


Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
115 KB
Volume
185
Category
Article
ISSN
1381-1169

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๐Ÿ“œ SIMILAR VOLUMES


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The synthesis of dimethyl carbonate by electrolytic carbonylation of CH,OH was performed using a PdCl,-added graphite anode in a gas mixture of CH,OH and CO at < 101 kPa and ambient temperature. The formation of dimethyl carbonate was initiated at an applied voltage across the cell greater than 0.3

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Dimethyl carbonate (DMC) synthesis by oxidative carbonylation of methanol has been studied using vapor phase flow reaction system in the presence of CuCl 2 /NaOH/AC (AC, activated carbon) catalysts. A series of CuCl 2 /NaOH/AC catalysts have been prepared by the conventional impregnation method with