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Redetermination of the structure of tetrakis(acetylacetonato)zirconium(IV)

โœ Scribed by Clegg, W.


Book ID
114504957
Publisher
International Union of Crystallography
Year
1987
Tongue
English
Weight
326 KB
Volume
43
Category
Article
ISSN
0108-2701

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Tetrakis(tert-butyl 3-oxobutanoato)ยญzirc
โœ Urs, Usha K. ;Dharmaprakash, M. S. ;Shivashankar, S. A. ;Guru Row, T. N. ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› International Union of Crystallography ๐ŸŒ English โš– 275 KB

The structure of the title compound, [Zr(C 8 H 13 O 3 ) 4 ], an MOCVD precursor, has been determined. The zirconium coordination geometry is dodecahedral and the chelate rings are signiยฎcantly non-planar. The Zr atom lies on a 4 axis, so the asymmetric unit contains only one ligand.