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Crystal and molecular structure of tetrakis-(O, O′-diisopropyldithio phosphates) of niobium (IV) and zirconium (IV)

✍ Scribed by V. V. Tkachev; S. A. Shchepinov; L. O. Atovmyan


Publisher
SP MAIK Nauka/Interperiodica
Year
1978
Tongue
English
Weight
342 KB
Volume
18
Category
Article
ISSN
0022-4766

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Preparation, characterization, crystal a
✍ Giorgio Anderegg; Edgar Müller; Kurt Zollinger; Hans-Beat Bürgi 📂 Article 📅 1983 🏛 John Wiley and Sons 🌐 German ⚖ 330 KB

The title compound and its potassium analog have been prepared from corresponding aqueous solutions of 9 T c 0 , at p H z 2 with SO2 as a reducing agent. An X-ray structure determination of the Na-salt showed Tc coordinated to the tetradentate N (CH,COO)Z-ligand (NTA). Two Tc-NTA moieties are joined