In the title compound, C 16 H 15 N 5 Á4H 2 O, the two independent molecules of the asymmetric unit are linked into a threedimensional structure by a combination of classical hydrogen bonds, C-HÁ Á Á and aromaticinteractions.
Redetermination of bis(benzimidazol-2-ylmethyl)amine
✍ Scribed by Tarazon Navarro, Ana ;McKee, Vickie
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 299 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title compound, C 16 H 15 N 5 , has been redetermined from data collected at 150 K. It crystallizes in space group Pbca, with four molecules in the unit cell, and the molecule is disordered about a centre of symmetry.
📜 SIMILAR VOLUMES
In the title crystal structure, C 16 H 17 N 5 2+ ÁSO 4 ## 2À , cations and anions are linked via N-HÁ Á ÁO hydrogen bonds, while ion pairs form extended one-dimensional chains through intermolecular N-HÁ Á ÁN hydrogen bonds.
N,N 0 0 0 -Bis(benzimidazol-1-ium-2-ylmethyl)-N,N 0 0 0 -bis(benzimidazol-2-ylmethyl)cyclohexane-1,2-trans-diamine bis(perchlorate) dihydrate
In the title molecule, C 15 H 12 N 4 , the two essentially planar benzimidazolyl moieties make a dihedral angle of 63.53 (2) . Intermolecular N-HÁ Á ÁN hydrogen bonds stabilize the crystal packing.