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Red shifts in the optical spectra of porphyrin Schiff's bases upon protonation

✍ Scribed by Ward, Brian; Callahan, Patricia M.; Young, Richard; Babcock, Gerald T.; Chang, C. K.


Book ID
120280718
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
396 KB
Volume
105
Category
Article
ISSN
0002-7863

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Reproducible proton chemical shifts in the porphyrin series are obtained when the spectrum is measured in chloroform using the zinc (11) complex of the porphyrin in the presence of an excess of pyrrolidine. This method is specifically demonstrated for the case of 2,4-dicyanodeuteroporphyrin-M dimeth