Recombination Dynamics and Hydrogen Abstraction Reactions of Chlorine Radicals in Solution
โ Scribed by Sheps, Leonid; Crowther, Andrew C.; Elles, Christopher G.; Crim, F. Fleming
- Book ID
- 120304535
- Publisher
- American Chemical Society
- Year
- 2005
- Tongue
- English
- Weight
- 215 KB
- Volume
- 109
- Category
- Article
- ISSN
- 1089-5639
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๐ SIMILAR VOLUMES
We wish to report evidence on the behaviour of initially formed radicals in photochemical reactions of henzophenone (I) and camphorquinone (CQ). Both of these compounds abstract hydrogen' from a variety of hydroqen donors via their n,n\* triplet states. For
Rate constants have been measured by pulse radiolysis for the reactions of the NO, radical with five cyclic ethers and a series of alcohols. Rate constants ranged from 3.5 x lo4 M-' 5 -l for deuterated methanol to 1.1 x lo7 M-' 5-l for tetrahydrofuran. The rate constants for the reactions of NO3 wit