Recoil tritium reactions at extremely low pressures
โ Scribed by E.-C. Wu; J.W. Anderton; A.A. Rudnicki; Y.-N. Tang
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- English
- Weight
- 245 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
โฆ Synopsis
Recotl tritium reactions with cyclobutane and ethyl chloride have been extended to pressures as low as 5 X 10e2 torr.
The results indrcate that more than 85% of the excited molecules subsequent to T-for-H substrtutton have e\crtatton energies higher than 2.6 eV.
๐ SIMILAR VOLUMES
Ion-molecule reactions at very low energies (<lo-\* eV) are investigated quantum-mechanically, taking the reaction H-+H+H2 t e as an example. Quantum effects, the zero-energy limit of the cross section, and the validity of an orbiting model are examined. Tbe orbiting model is found to be satisfactor
The thermal decomposition of cyclobutyl chloride has been investigated over the temperature range of 892-1150 K using the technique of very low-pressure pyrolysis (VLPP). The reaction proceeds via two competitive unimolecular channels, one to yield ethylene and vinyl chloride and the other to yield
Pressure-dependent solubility and diffusion coefficients for carbon dioxide in glassy polymers have been well described using the ''dual sorption and transport model.'' However, the plastisization effect by high-pressure carbon dioxide seems to promote the pressure dependence of the sorption and tra