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Recherches sur la formation et les transformations des esters. XI. Note sur la variation de la vitesse d'hydrolyse des acides monoalcoylphosphoriques en fonction du pH

✍ Scribed by Emile Cherbuliez; J. Rabinowitz

Publisher
John Wiley and Sons
Year
1957
Tongue
German
Weight
174 KB
Volume
40
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

Some arguments are advanced to show that the curve representing the apparent constants of the rate of hydrolysis of monoalkyl phosphoric acids as function of the pH offers not only the well known minimum at about pH 0 and maximum at pH 4·5, but a second minimum at high pH. The interpretation of this curve requires the intervention of at least three mechanisms of hydrolysis, such as acidolysis, halolysis and basolysis, as postulated earlier by the authors, apart from hydrolysis sensu stricto.

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