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Recent developments in microwave-assisted polymerization with a focus on ring-opening polymerization

✍ Scribed by Zhang, Chao; Liao, Liqiong; Gong, Shaoqin (Sarah)


Book ID
111903032
Publisher
Royal Society of Chemistry
Year
2007
Tongue
English
Weight
416 KB
Volume
9
Category
Article
ISSN
1463-9262

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Microwave-Assisted Ring-Opening Polymeri
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## Abstract **Summary:** Microwave‐assisted ring‐opening polymerization of __ε__‐caprolactone in the presence of 1‐butyl‐3‐methylimidazolium tetrafluoroborate ionic liquid using zinc oxide as a catalyst is investigated. By adding 30 wt.‐% ionic liquid, poly(__ε__‐caprolactone) with a weight‐average

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## Abstract PCL/clay nanocomposites were prepared by microwave‐assisted in situ ROP of __ε__‐caprolactone in the presence of either unmodified clay (Cloisite® Na^+^) or clay modified by quaternary ammonium cations containing hydroxyl groups (Cloisite 30B). This PCL showed significantly improved mon