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Recalculated rate parameters for the anation reaction of aquopentaamminecobalt(III) by some carboxylic acids in aqueous acidic solution

โœ Scribed by R. van Eldik

Book ID
115974329
Publisher
Elsevier Science
Year
1976
Weight
218 KB
Volume
38
Category
Article
ISSN
0022-1902

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The kinetics of the anation reaction of
The kinetics of the anation reaction of aquopentaamminecobalt(III) by malonate in acidic aqueous solution
โœ P. R. Joubert; R. Van Eldik ๐Ÿ“‚ Article ๐Ÿ“… 1976 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 470 KB ๐Ÿ‘ 1 views

The Co(NH3) 50Hz3+ ion reacts with malonate to form Co(NH3) 50~CCH2C02H2+ or Co(NH3) 50ZCCHzCOz+, depending on the pH of the reaction solution. The kinetics of this anation reaction have been studied as a function of [H+] for the acidity range 1.5 5 pH 5 6.0 in the temperature range of 60 to 8OoC, t