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Reassignment of structure to the Scholtz "pyrrolo[1,2-a]indole"

✍ Scribed by Franck, Richard W.; Sister Jeanne Marie Gilligan,


Book ID
127006291
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
452 KB
Volume
36
Category
Article
ISSN
0022-3263

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## Abstract Heating of 1′‐(__N__‐substituted carbamoyl)methylspiro[2__H__‐1‐benzopyran‐2,2′‐[2__H__]indoles] with potassium hydroxide in ethanol yields diastereomeric 5a,13‐methano‐6__H__‐1,3‐benzoxazepino[3,2‐__a__]indole‐12‐carbox‐amides. Reduction of the latter with sodium borohydride affords 1,