𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Rearrangements of 4-alkynyl-, 4-alkenyl-, and 4-alkyl-4-hydroxy-3-methylenecyclobutenes

✍ Scribed by Ezcurra, John E.; Pham, Christine; Moore, Harold W.

Book ID
126171530
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
362 KB
Volume
57
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Decarboxylation in the synthesis of 4-al
Decarboxylation in the synthesis of 4-alkyl-, 4-alkenyl- and 4-acylpyrimidines
✍ Gunnar Herstad; Tore Benneche 📂 Article 📅 2003 🏛 Journal of Heterocyclic Chemistry 🌐 English ⚖ 72 KB

## Abstract Decarboxylation of allylic esters of 4‐carboxypyrimidines in toluene at 111 °C in the presence of a Pd(0) catalyst, gives a mixture of a 4‐alkenylpyrimidine and a pyrimidine unsubstituted in the 4‐position. If the decarboxylation is carried out in the presence of benzaldehyde, then benz

3-Hydr­oxy-4-nitro­phenyl 4-toluene­sulf
3-Hydr­oxy-4-nitro­phenyl 4-toluene­sulfonate
✍ Ji, Xiujie ;Li, Chunbao ;Liu, Chao 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 97 KB

In the molecule of the title compound, C 13 H 11 NO 6 S, an intramolecular O-HÁ Á ÁO hydrogen bond is formed between the hydroxy group and the nitro O atom. The two aromatic rings form a dihedral angle of 48.8 (2) .

3-Chloro-4-hydr­oxy-4′-methyl­benzopheno
3-Chloro-4-hydr­oxy-4′-methyl­benzophenone
✍ Harrison, William T. A. ;Anilkumar, H. G. ;Yathirajan, H. S. ;Sadashivamurthy, B 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 368 KB

The title compound, C 14 H 11 ClO 2 , possesses normal geometrical parameters. The two benzene rings are twisted by 54.70 (4) , perhaps as a result of steric repulsion between H atoms. The crystal packing is consolidated by an O-HÁ Á ÁO hydrogen bond,stacking and C-HÁ Á ÁO and C-HÁ Á Á interactions,