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Rearrangements of 2,6-Dimethyl- and 2,3,4,6-Tetramethylbenzyltrimethylammonium Ions with Sodium Amide and Reactions of the Products 1

โœ Scribed by HAUSER, CHARLES R.; EENAM, DONALD N. VAN

Book ID
121277008
Publisher
American Chemical Society
Year
1958
Tongue
English
Weight
631 KB
Volume
23
Category
Article
ISSN
0022-3263

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The title reactions furnished the pyran ring cleaved product (3) and the tetracyclic chromene (5), rather than the expected 4-cyclicamido-3hydroxy benzopyrans (l,R=CN and NO2, respectively, n=ll). Mechanisms proposed for these reactions require a strong electron withdrawing group at C(6) in the benz