Rearrangements of 2- and 3-Furfurylidene
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Albers, Reinhard ;Sander, Wolfram
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Article
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1997
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John Wiley and Sons
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English
⚖ 377 KB
## Abstract The photo‐ and thermochemistry of diazo(2‐furyl)methane (3) and diazo(3‐furyl)methane (6) was investigated using the matrix isolation technique. Photolysis of 3 results in the formation of (__Z__)‐pent‐2‐en‐4‐yn‐1‐al (2) in a clean reaction, in agreement with the observation of Shechter