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ChemInform Abstract: Rearrangements of 2- and 3-Furfurylidene.

✍ Scribed by R. ALBERS; W. SANDER


Publisher
John Wiley and Sons
Year
2010
Weight
25 KB
Volume
28
Category
Article
ISSN
0931-7597

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Rearrangements of 2- and 3-Furfurylidene
✍ Albers, Reinhard ;Sander, Wolfram πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 377 KB

## Abstract The photo‐ and thermochemistry of diazo(2‐furyl)methane (3) and diazo(3‐furyl)methane (6) was investigated using the matrix isolation technique. Photolysis of 3 results in the formation of (__Z__)‐pent‐2‐en‐4‐yn‐1‐al (2) in a clean reaction, in agreement with the observation of Shechter