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Rearrangements in the molecular ion of o-(methyl-d3-thio)benzoic Acid: Comparison with o-methoxy-d3-benzoic acid

✍ Scribed by Richard G. Gillis; Quentin N. Porter


Publisher
John Wiley and Sons
Year
1985
Tongue
English
Weight
239 KB
Volume
20
Category
Article
ISSN
1076-5174

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Synthesis of [2H13]heptanoic acid via th
✍ Hirohisa Tsuzuki; Mamoru Mukumoto; Takehito Tsukinoki; Shuntaro Mataka; Masashi 📂 Article 📅 1994 🏛 John Wiley and Sons 🌐 French ⚖ 222 KB

## Abstract [^2^H~13~]Heptanoic acid was synthesized as its methyl ester (4) (deuterium content: 96%) with Ni‐Al alloy in 10% NaOD‐D~2~O __via__ the desulfurization of methyl 3‐chloro‐5,6‐dibromothieno[3,2,__b__]thiophene‐2‐carboxylate (3), which was derived from 4,5‐dibromothiophene‐2‐carboaldehyd