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Rearrangements in Carbonium Ion-Type Reactions of C 14 -Labeled Dehydronorbornyl Derivatives 1

โœ Scribed by Roberts, John D.; Lee, C. C.; Saunders, W. H.

Book ID
126999377
Publisher
American Chemical Society
Year
1955
Tongue
English
Weight
534 KB
Volume
77
Category
Article
ISSN
0002-7863

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Evidence for a carbonium ion rearrangeme
Evidence for a carbonium ion rearrangement in the reaction of triisobutylaluminum and 1,3,3-trimethylcyclopropene
โœ Herman G. Richey Jr.; Barry Kubala; Mark A. Smith ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 212 KB

Formation of acyclic products in the reaction of triisobutylaluminum and 1,3,3trimethylcyclopropene can reasonably be ascribed to a carbonium ion rearrangement. This suggestion supports the mechanism for carbalumination of alkenes proposed by Eisch.