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Rearrangements from the reactions of silenes with trimethylsilylketene

✍ Scribed by A.G. Brook; Alfred Baumegger


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
249 KB
Volume
446
Category
Article
ISSN
0022-328X

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✍ Kiyo Takaoka; Toyohiko Aoyama; Takayuki Shioiri πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 28 KB πŸ‘ 2 views

Reaction of Nitrones with Trimethylsilylketene. -Trimethylsilylketene reacts smoothly with diarylnitrones (I) to give oxindoles. Mixtures of N,N-diacylamines (V) and N-acylamines (VI) are formed with N-arylmethylnitrones (IV). The mechanism is discussed. -(TAKAOKA,