Rearrangements between Primary Ethanolamides of Carboxylic Acids and the Corresponding Aminoethylesters *
โ Scribed by Phillips, Arthur P.; Baltzly, Richard
- Book ID
- 126984339
- Publisher
- American Chemical Society
- Year
- 1947
- Tongue
- English
- Weight
- 559 KB
- Volume
- 69
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
The product 4,4-di-tert-butyl-3-methyl-4H-l,2-oxazete 2oxide (2) is the first derivative of the new system 4H-1.2-. oxazete. It was isolated in quantitative yield when a solution of ( I ) in ethanol, after having been allowed to stand overnight, was evaporated down and the residue recrystallized fr
Ab4tic.Z . 2-Trimethylsilylethanol was used to trap isocyanates produced by the Curtius rearrangement of acyl azides and the resulting trimethylsilylethyl carbamates were readily cleaved with tetra-n-butylammonium fluoride to liberate the primary amines.