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Rearrangements and fragmentations of metastable [C13H9S]+, [C14H11]+, [C13H11]+ and [C8H7S]+ ions

✍ Scribed by Marcel Rietjens; Drewes Oudman; Wilke D. Weringa

Publisher
John Wiley and Sons
Year
1990
Tongue
English
Weight
334 KB
Volume
25
Category
Article
ISSN
1076-5174

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✦ Synopsis

Abstract

[C~13~H~9~S]^+^, [C~14~H~11~]^+^, [C~13~H~11~]^+^ and [C~8~H~7~S]^+^ ions with unknown structures were generated from two [C~14~H~12~S]^+Β·^precursor ions by fragmentation reactions that must be preceded by extensive rearrangements. Ions with the same compositions, each with several initial structures, were prepared by simple bond‐breaking reactions. Metastable characteristics were compared for each of the four types of ions. It was found than in all cases fast isomerization reactions occur prior to fragmentation, so that no information about the unknown ion structures could be obtained by comparison of the observed fragmentations of metastable ions.

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