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Rearrangement of cyclobutyl carbinyl radicals: Total synthesis of the spirovetivane phytoalexin (±)-lubiminol

✍ Scribed by Michael T Crimmins; Zhuo Wang; Lynne A McKerlie

Book ID
104255816
Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
223 KB
Volume
37
Category
Article
ISSN
0040-4039

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ChemInform Abstract: Rearrangement of Cy
ChemInform Abstract: Rearrangement of Cyclobutyl Carbinyl Radicals: Total Synthesis of the Spirovetivane Phytoalexin (.+-.)-Lubiminol.
✍ M. T. CRIMMINS; Z. WANG; L. A. MCKERLIE 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB

Rearrangement of Cyclobutyl Carbinyl Radicals: Total Synthesis of the Spirovetivane Phytoalexin (±)-Lubiminol. -The total synthesis of title compound (VI) relies on the intramolecular photolytic (2 + 2) cycloaddition of the key intermediate (I). The stereoselectively resulting photoadduct (II) is t

Stereocontrolled total synthesis of (±)-
Stereocontrolled total synthesis of (±)-lubiminol, a spirovetivane phytoalexin
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A total synthesis of (+)-lubiminol, one of the spirovetivane phytoalexins, was accomplished under a high stereocontrol of all five asymmetric carbon centers.

ChemInform Abstract: Double Diastereosel
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✍ M. T. CRIMMINS; Z. WANG; L. A. MCKERLIE 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 41 KB 👁 1 views

## Double Diastereoselection in Intramolecular Photocycloadditions: A Radical Rearrangement Approach to the Total Synthesis of the Spirovetivane Phytoalexin (±)-Lubiminol. -Key steps in the synthesis of the title compound (XIII) are a conjugate addition-cyclization reaction to prepare compound (I