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ChemInform Abstract: Rearrangement of Cyclobutyl Carbinyl Radicals: Total Synthesis of the Spirovetivane Phytoalexin (.+-.)-Lubiminol.

โœ Scribed by M. T. CRIMMINS; Z. WANG; L. A. MCKERLIE

Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
28
Category
Article
ISSN
0931-7597

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โœฆ Synopsis

Rearrangement of Cyclobutyl Carbinyl Radicals: Total Synthesis of the Spirovetivane Phytoalexin (ยฑ)-Lubiminol.

-The total synthesis of title compound (VI) relies on the intramolecular photolytic (2 + 2) cycloaddition of the key intermediate (I). The stereoselectively resulting photoadduct (II) is transformed to the required spiro(5.4)decane system (V) through a radical fragmentation rearrangement reaction of (IV). -(CRIMMINS, M. T.;

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