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Rearrangement of .alpha.-ethynyl alcohols to unsaturated carbonyl compounds (The Rupe Reaction)

✍ Scribed by Hasbrouck, Richard W.; Anderson, Ann D.


Book ID
126922922
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
609 KB
Volume
38
Category
Article
ISSN
0022-3263

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The Rearrangement of Ξ±-Acetylenic Alcoho
✍ Horst Pauling; David Arthur Andrews; Nathan Chadwick Hindley πŸ“‚ Article πŸ“… 1976 πŸ› John Wiley and Sons 🌐 German βš– 741 KB

## Abstract New catalytic systems have been found which effect the isomerization of α‐acetylenic alcohols to the corresponding Ξ±, β‐unsaturated carbonyl compounds with high efficiency. These are combinations of silylvanadates with silanols or silanediols.