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Rearrangement of a 1,4-thiazepine ring and formation of 3-isothiazolones

✍ Scribed by N.J. Leonard; G.E. Wilson Jr

Book ID
104215068
Publisher
Elsevier Science
Year
1964
Tongue
French
Weight
26 KB
Volume
5
Category
Article
ISSN
0040-4039

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## Abstract A new one‐pot synthesis of title compounds 2 by reaction of β‐aminothiocinnamic acid anilides 1 with α‐haloacid halides is described. The ring of 1,4‐thiazepine 2 in basic medium undergoes transformation to thiazolidin‐4‐ones 5.