Rearrangement of 4-Methyl-4-trichloromethyl-2,5-cyclohexadienols 1,2
β Scribed by Newman, Melvin S.; Eberwein, John; Wood, Louis L.
- Book ID
- 121865667
- Publisher
- American Chemical Society
- Year
- 1959
- Tongue
- English
- Weight
- 406 KB
- Volume
- 81
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
Ultraviolet irradiation of the title compounds in amine solvents results in transformations attributed to initial formation of radical ions by electron transfer, the quantum efficiency of reaction depending on the ionization potential of the amine. Cross-conjugated cyclohexadienones have been the su
A series of 5-trichloro-D 4 -1,2,4-oxadiazolines have been synthesised by 1,3-dipolar cycloaddition of nitrones to trichloroacetonitrile. These oxadiazolines rearrange into formamidine derivatives, via ring opening and a 1,2-aryl shift from carbon to the adjacent amino nitrogen. Both cycloaddition a