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Thermal aromatizational rearrangements of 4,4-dimethyl-l-(4-trichloromethyl-4-methylcyclohexa2,5-dienylidene cyclohexane-2,6-dione

โœ Scribed by V. A. Nikanorov; S. V. Sergeev; P. V. Petrovskii; D. V. Zverev; N. A. Klyuev; A. L Gamzazade; G. E. Vainer; F. M. Dolgushin; A. I. Yanovskii; Yu. T. Struchkovt

Book ID
112537412
Publisher
Springer
Year
1996
Tongue
English
Weight
165 KB
Volume
45
Category
Article
ISSN
1573-9171

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Selective rearrangements of 4a,5-epoxide
Selective rearrangements of 4a,5-epoxides of 4,4-dimethyl-1,2,3,4,6,8a-hexahydronaphthalenes.
โœ Steven P. Tanis; Yousef M. Abdallah; Paul G. Williard ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 303 KB

g oxidation selectivity of a number of 4 r-dimethyl-1,2,3,4,6,8a-hexahydronapht alenes 4 were examined. Exposure of the isolated a-epoxides 7 provided excellent yields (79-92x) of rearranged fused indene-oxetanes 8. Treatment of dF\_epoxides 5 with BF3\* OEtz also yields oxetanes 6 and related alcoh