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Rearrangement of 2,6-dibromocyclohexanone ketals

โœ Scribed by Graff, Mark; Gilligan, William H.

Book ID
127344046
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
267 KB
Volume
32
Category
Article
ISSN
0022-3263

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๐Ÿ“œ SIMILAR VOLUMES

Rearrangement of 2-bromotropone ketals
Rearrangement of 2-bromotropone ketals
โœ John E. Baldwin; James E. Gano ๐Ÿ“‚ Article ๐Ÿ“… 1969 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 149 KB

Salaun and Conia (4) have Just reported that several 2-bromocyclobutanone ketals rearrange thermally to give cyclopropanecarboxylates and alkyl bromides.

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Functionalized ketals participate successfully in the acid-catalyzed ketal Claisen rearrangement to afford mixtures of the isomeric Y,6vnsaturated ketones, with the more highly substituted isomer predominating by a factor of 2-4:l.