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Ketal Claisen rearrangements of simple aliphatic ketals

โœ Scribed by Daub, G. William; McCoy, Mark A.; Sanchez, Michael G.; Carter, James S.

Book ID
126210588
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
1005 KB
Volume
48
Category
Article
ISSN
0022-3263

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๐Ÿ“œ SIMILAR VOLUMES

Ketal claisen rearrangements of function
Ketal claisen rearrangements of functionalized ketals
โœ G.William Daub; Sharon R. Lunt ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 231 KB

Functionalized ketals participate successfully in the acid-catalyzed ketal Claisen rearrangement to afford mixtures of the isomeric Y,6vnsaturated ketones, with the more highly substituted isomer predominating by a factor of 2-4:l.

Rearrangement of 2-bromotropone ketals
Rearrangement of 2-bromotropone ketals
โœ John E. Baldwin; James E. Gano ๐Ÿ“‚ Article ๐Ÿ“… 1969 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 149 KB

Salaun and Conia (4) have Just reported that several 2-bromocyclobutanone ketals rearrange thermally to give cyclopropanecarboxylates and alkyl bromides.