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Rearrangement of 2-methyl-2,3-epoxypentane: a kinetic study

✍ Scribed by Kurtev, Kurti ;Kehayova, Darina ;Mitkova, Magdalena ;Tomov, and Atanas

Book ID
111606138
Publisher
Springer
Year
2004
Tongue
English
Weight
79 KB
Volume
81
Category
Article
ISSN
0133-1736

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✍ John O. Morley; A. Jayne Oliver Kapur; Michael H. Charlton πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 265 KB

## Abstract The kinetics of the ring‐opening reactions of the 3‐isothiazolones (**1a–d**) with aqueous 2‐methyl‐2‐propanethiol has been explored at pH 4. The results strongly suggest that the reaction is second order in thiol and third order overall. Extrapolation of the kinetic data gives third‐or