𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Rearrangement of 1,1'-spirobiindene and thermochemical evidence for its spiroconjugative destabilization

✍ Scribed by Hill, Richard K.; Morton, Gerald H.; Rogers, Donald W.; Choi, Ling S.


Book ID
127337151
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
548 KB
Volume
45
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Homo- and spiroconjugative effects in th
✍ Herbert Kiesele πŸ“‚ Article πŸ“… 1981 πŸ› Elsevier Science 🌐 French βš– 218 KB

Due to homoconjugative interactions 2,3-dihydro-l,'l'-spirobiindene and 'l,l'-spirobiindene yield isomeric benzofluorenes in thermal, photochemical, and electron transfer induced rearrangement. Recently it was shown that the electron transfer induced rearrangement of l,ldisubstituted indenes proceed

Evidence for a carbonium ion rearrangeme
✍ Herman G. Richey Jr.; Barry Kubala; Mark A. Smith πŸ“‚ Article πŸ“… 1981 πŸ› Elsevier Science 🌐 French βš– 212 KB

Formation of acyclic products in the reaction of triisobutylaluminum and 1,3,3trimethylcyclopropene can reasonably be ascribed to a carbonium ion rearrangement. This suggestion supports the mechanism for carbalumination of alkenes proposed by Eisch.