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Rearrangement during the process of thermal telomerization of ethylene with silicon hydrides

โœ Scribed by R. Kh. Freidlina; Yu. P. Egorov; E. Ts. Chukovskaya; I. Tsao; E. D. Lubuzh

Book ID
112483963
Publisher
Springer
Year
1961
Tongue
English
Weight
379 KB
Volume
10
Category
Article
ISSN
1573-9171

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Silicon in organic synthesis. 14. Five r
Silicon in organic synthesis. 14. Five ring annulation processes based upon thermal rearrangement of (1-trimethylsilylcyclopropyl)ethylenes
โœ Leo A Paquette; Gregory J Wells; Keith A Horn; Tu-Hsin Yan ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 234 KB

Pyrolysis of (1-trlmethylsllylcyclopropyl)ethylenes affords silyl substituted cyclopentenes In high yield. Subsequent reaction of these products with varied electrophiles forms the basis of a new and versatile five-ring annulation sequence.