✦ LIBER ✦
Silicon in organic synthesis. 14. Five ring annulation processes based upon thermal rearrangement of (1-trimethylsilylcyclopropyl)ethylenes
✍ Scribed by Leo A Paquette; Gregory J Wells; Keith A Horn; Tu-Hsin Yan
- Book ID
- 104220304
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- French
- Weight
- 234 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Pyrolysis of (1-trlmethylsllylcyclopropyl)ethylenes affords silyl substituted cyclopentenes In high yield. Subsequent reaction of these products with varied electrophiles forms the basis of a new and versatile five-ring annulation sequence.