Real-time simplex optimization of square wave voltammetry
β Scribed by K.H. Wong; Robert A. Osteryoung
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 275 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0013-4686
No coin nor oath required. For personal study only.
β¦ Synopsis
A simplex optimization procedure has been applied to square wave voltammetric on-line measurements; the objective function maxim&d half-height.
is the ratio of the square wave peak current to the width at
π SIMILAR VOLUMES
The effects of changing certain parameters of the applied potential waveform at a dropping mercury electrode (DME) in square-wave voltammetry (s.w.v.) were investigated and compared with theory. Optimum parameters of the waveform are determined for a reversible system, lead(I1) in 0.10 M perchloric
Square-wave voltammetric measurements of the Eu(III)-salicylate (Eu-Sal) complex in 0.55 mol 1-l NaCl at pH 5.3 were made. At various europium concentration levels (from 10-s to 10e6 mol 1-r) the redox process of the Eu-Sal complex is reversible, with adsorption of the reactant of the redox reaction