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Real-time monitoring of laser photochemical reactions of polyvinylchloride

✍ Scribed by L. Sheu; K. Imen; S. D. Allen


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
126 KB
Volume
77
Category
Article
ISSN
0021-8995

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✦ Synopsis


The formation of conjugated double bonds in polyvinylchloride (PVC) films by ultraviolet (UV) irradiation is analyzed using an in situ laser-monitoring technique we have developed to measure changes in transmittance of thin UV-irradiated PVC films. Conjugated polyenes of different lengths are produced by laser irradiation at 193 and 248-nm wavelengths. This technique promises to have broader applications in the study of polymer reaction mechanisms and kinetics.


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