Real-time monitoring of laser photochemical reactions of polyvinylchloride
β Scribed by L. Sheu; K. Imen; S. D. Allen
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 126 KB
- Volume
- 77
- Category
- Article
- ISSN
- 0021-8995
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β¦ Synopsis
The formation of conjugated double bonds in polyvinylchloride (PVC) films by ultraviolet (UV) irradiation is analyzed using an in situ laser-monitoring technique we have developed to measure changes in transmittance of thin UV-irradiated PVC films. Conjugated polyenes of different lengths are produced by laser irradiation at 193 and 248-nm wavelengths. This technique promises to have broader applications in the study of polymer reaction mechanisms and kinetics.
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