✦ LIBER ✦

Real-time mass-spectrometric study of the chemistry initiated by infrared-laser photolysis: CF2Cl2

✍ Scribed by Richard I. Martinez; John T. Herron

Publisher: Elsevier Science
Year: 1983
Tongue: English
Weight: 565 KB
Volume: 98
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(83)87125-5

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✦ Synopsis

The rnfrxed-laer photol> sisimnss-spectrometric (ILP/MS) technique \ias used to monitor directly in real time the freer.kical and stabis rexrants and products present in the reactive system initiated by the multiphoton-induced dissociation of Cl~~C12 _ It 11 JS found that. contrary to conclusions b.wd on final-products analyses, the CzFa observed as a final product m thi\ s! stem is not formed solely thmuph the reconlbinatmn of :CI'z radicals, but rather C2F4 is produced in a complex writ\ of sccondar) rcxtions.

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