Reagent-Controlled Switching of 5-exo to 6-endo Cyclizations in Epoxide Openings
β Scribed by Yoshiki Morimoto; Yoshihiro Nishikawa; Chigusa Ueba; Takeshi Tanaka
- Publisher
- John Wiley and Sons
- Year
- 2006
- Tongue
- English
- Weight
- 105 KB
- Volume
- 118
- Category
- Article
- ISSN
- 0044-8249
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## Abstract Syntheses of the alcohols **10** and **18**, and the corresponding ketones **11** and **19** are presented. __Endo__β5, __exo__β6βbis (chloromethyl)β__endo__β3βchloroβ__exo__β2βnorbornanol (**16**) and __endo__β5β(bromomethyl)β__exo__β6β(chloromethyl)β__endo__β3βchloroβ__exo__β2βnorborn