ChemInform Abstract: Regiochemistry in Aryl Radical Cyclizations (5-exo versus 6-endo) of N-Vinylic 2-Iodobenzamides.
β Scribed by Hiroyuki Ishibashi; Kohei Ohata; Michiyo Niihara; Tatsunori Sato; Masazumi Ikeda
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 32 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0931-7597
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Effect of Temperature on 5-endo-and 4-exo-trig Radical Cyclizations of N-Vinylic Ξ±-Halo Amides. -The reaction course is found to depend on the temperature. The method provides a new entry to tetrahydroindoles as versatile synthetic intermediates.