Reagent control in the aldol addition re
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Cesare Gennari; Daniela Moresca; Anna Vulpetti; Gilles Pain
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Article
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1997
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Elsevier Science
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French
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Boron enolates bearing menthone-derived chiral ligands are capable of fair to excellent diastereocontrol in their reactions with chiral aldehydes. Thioester-derived (better than ketone derived) enolates are able to control aldol stereochemistry irrespective of the aldehyde preferences. With thioacet