Two-State Reactivity in the Rebound Step
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Nathan Harris; Shimrit Cohen; Michael Filatov; François Ogliaro; Sason Shaik
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Article
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2000
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John Wiley and Sons
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English
⚖ 119 KB
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Alkane hydroxylation [1] by cytochrome P-450 poses tantalizing mechanistic questions. The consensus rebound mechanism, Scheme 1, [2] involves hydrogen abstraction from the Scheme 1. Schematic representation of the rebound mechanism.