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Reactivity patterns in the reactions of [Rh(CO)2Cl]2 with chelating ketones

โœ Scribed by J.William Suggs; Michael J. Wovkulich; Paul G. Williard; Ken S. Lee


Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
733 KB
Volume
307
Category
Article
ISSN
0022-328X

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The infrared chemiluminescent reaction o
โœ D. M. Fasano; N. S. Nogar ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 377 KB ๐Ÿ‘ 1 views

## Abstract The reaction Cl + H~2~CO โ†’ HCl + HCO has been studied at 295 K. Chlorine atoms were produced via the infrared laser induced dissociation of CCl~3~F, using a pulsed CO~2~ TEA laser. Using HCl infrared chemiluminescence as the diagnostic, we find the rate constant to be 7.4 ยฑ 0.7 ร— 10^โˆ’11