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Reactivity of Transition Metal Fluorides. III. Higher Fluorides of Vanadium, Niobium, and Tantalum

✍ Scribed by Canterford, J. H.; O'Donnell, T. A.

Book ID: 125844949
Publisher: American Chemical Society
Year: 1966
Tongue: English
Weight: 653 KB
Volume: 5
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic50042a036

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effect). Thus, in place of the one ligand-field transition (Eg + Tzg) customary for octahedral symmetry, three transitions can occur ( E l , ' > A l , , E l g + B z ~, and B1, + Eg for an octahedron extended in the z-direction), and these can be recognized in the reflectance spectra of most of the c