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Reactivity of the unsaturated manganese dihydrides [Mn2(μ-H)2(CO)6(μ-L2)](L2 = Ph2PCH2PPh2 or (EtO)2POP(OEt)2) towards small molecules

✍ Scribed by Francisco J. García Alonso; Manuel García Sanz; Xiang Yiang Liu; Alberto Oliveira; Miguel A. Ruiz; Victor Riera; Claudette Bois


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
774 KB
Volume
511
Category
Article
ISSN
0022-328X

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Synthesis, Structure, and Reactivity of
✍ Dr. Francisco J. García Alonso; Dr. Manuel García Sanz; Prof. Victor Riera; Dr. 📂 Article 📅 1988 🏛 John Wiley and Sons 🌐 English ⚖ 237 KB 👁 1 views

H,-elimination from 3 must also occur [Eq. (e)]."ll Note that this equilibrium involves the same 16-electron species implicated in Equation (c). The product-forming hydrido-ethyl (A) and hydridoethyl ethylene (B) species (Scheme 1) "downstream" of reaction (d) have not been observed under a variety