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Reactions of the unsaturated dihydrides [Mn2(μ-H)2(CO)6(μ-L2)](L2 = (EtO)2POP(OEt)2, Ph2PCH2PPh2) with phosphines containing PH bonds

✍ Scribed by Remedios Carreño; Victor Riera; Miguel A. Ruiz


Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
612 KB
Volume
419
Category
Article
ISSN
0022-328X

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Synthesis, Structure, and Reactivity of
✍ Dr. Francisco J. García Alonso; Dr. Manuel García Sanz; Prof. Victor Riera; Dr. 📂 Article 📅 1988 🏛 John Wiley and Sons 🌐 English ⚖ 237 KB 👁 1 views

H,-elimination from 3 must also occur [Eq. (e)]."ll Note that this equilibrium involves the same 16-electron species implicated in Equation (c). The product-forming hydrido-ethyl (A) and hydridoethyl ethylene (B) species (Scheme 1) "downstream" of reaction (d) have not been observed under a variety