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Reactivity of the metal-carbon bonds in the metallacycles [(Me3Si)2N]MCH2Si(Me)2NSiMe3

✍ Scribed by Alain Dormond; Abdel Aziz El Bouadili; Claude Moise


Book ID
116015938
Publisher
Elsevier Science
Year
1986
Weight
406 KB
Volume
122
Category
Article
ISSN
0022-5088

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On the Staudinger Reaction of SP(N3)3 wi
✍ Nadine GΓΆtz; Sebastian Herler; Peter Mayer; Axel Schulz; Alexander Villinger; Ja πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 187 KB

## Abstract The Staudinger reactions of SP(N~3~)~3~ (1) with 1, 2 and 3 equiv. of triphenylphosphane PPh~3~ and (TMS)~2~N–(TMS)N–PPh~2~ (2) have been investigated (TMS = Me~3~Si). Reaction with PPh~3~ yields the single and double Staudinger products SP(N~3~)~2~NPPh~3~ (3) and SP(N~3~)(NPPh~3~)~2~ (